If you scroll down through this
http://old.akronschools.com/dotAsset/71247.pdf
you will find the list of ingredients for miracid. In australia they have to list the percentage of urea used in the products, I haven't seen miracid on the shelves for a long time, but it was something like 50% urea in composition, hence the 30-10-10 claim.
The product is designed for use on the ground, not in pots.
Urea is broken down into ammonia in the soil by an enzyme called urease, which is released by bacteria into the soil. In agriculture urea is generally mixed into the soil to prevent N loss as ammonia is a highly insoluble gas; and is highly alkaline. So the breakdown of urea actually raises soil pH initially. Losses of N from agriculture use due to ammonia volatilization where it hasn't been incorporated into the soil has been measured as high as 90%.
What happens next depends on the soils pH. If it is alkali then the ammonium carbonate just hangs around. If the soil is acidic then the ammonia reacts with soil acids to form ammonium. This is then taken up by plants. The +ve charge of the ammonium ion is balanced by the release of acidity by plant roots, which lowers soil pH slightly.
see page 4 of this for complete chemical reactions, note the production of ammonium carbonate and the consumption of 2 acid molecules to produce ammonium. Making a net alkali reaction.
http://www.soils.wisc.edu/extension/materials/ReduceVolLoss.pdf
Check page 6 for soil pH changes, note the rise in soil pH. The claims by Scotts that it reduces soil pH is wrong, and they don't ever explain how there product lowers soil pH.
The Holly Tone product looks good. But the reality is, using an acidifying product once a month, or twice a year will do absolutely nothing for the health of your plant. It is the level of alkalinity (bicarbonate) in the water that pushes soil pH up, and the type of fertilizer you use routinely that pushes pH down.
Poink88's water analysis shows high pH, but most importantly it shows low alkalinity at an avg of 57. Water pH is a very weak force compared to plant roots and soil buffering. So he can water with pH 9.6 and it won't affect the overall soil pH as long as he uses a fertilizer with some ammonium in it.
A tablespoon of vinegar once a month does nothing for your plants.
Unless you routinely measure your soil pH you really don't know what is happening in your soils. If your plants are growing well, then chances are that you don't have a pH issue and don't need to mess with this stuff.
Anyone who has had alkalinity issues with their water will tell you how hard it is to reduce soil pH. It's not a simple as adding some vinegar once a month.
Paul